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Paul RakoTechnical Editor Paul Rako looks at analog technology in power supplies, interface, the signal path, and life in general.



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Thursday, August 14, 2008

MIT says electrolysis is a solar energy breakthrough

Aug 14 2008 4:47AM | Permalink |Comments (18) |


OK, I don’t want to be negative Nellie here, but I am truly befuddled with the amount of hype and BS surrounding anything to do with alternative energy. Here is an article from ABC about a solar breakthrough. I read and re-read it and forgive me, I just don’t get it. It is wrong on so many levels it defies comprehension. Just to make sure I was not taking crazy pills, I looked up the original MIT press release here. OK, this professor has discovered an inexpensive catalyst that assists in electrolysis. And he and MIT claim this is a major breakthrough for solar energy. They say that solar cells can use this breakthrough process to make hydrogen during the day and then we, as a happy obedient society can use the hydrogen at night, I suppose to burn dirigibles so we can read our parchment newspapers since we can’t afford electricity any more.

OK, where to start? First off, solar energy is not held back since it cannot make power at night. Oh, if you are some Ted Kazinsky Unabomber type that wants to live in a cabin off the grid, well I guess that fact that there is no solar power at night is a bit problematic. But any sane person does what is the sensible thing: You tie your solar installation to the grid and pump energy in the grid during the day while taking it out at night. Turns out that PG&E is perfectly happy with this, their big problem is that peak power occurs in the day and they love to have the solar energy in the day in order to even out the load on their generators. So you pump in all your excess into the grid. And it is much more than just a nighttime problem. See, the power from your solar array is also dependent on season; you get more in the summer. This also makes PG&E, your willing partner in solar energy, very happy since summertime peak loads are usually worse due to all the air conditioners being run. The idea is that you pump in enough energy during summer to days to build up a big bank of power so you can draw it back out at night and over the winter. It may be temping to try and zero out your electric bill, but that is usually very poor economics. You would need about $50,000 installation of panels here in California to do that, as my buddy Frank has done up in Grass Valley. What you really want to do is keep your electricity usage under the monthly rate caps—what PG&E calls you baseline rate, a chunk of kilowatt hours allowed your home based on location. This is because solar power still does not payout for the 13 cents a kilowatt-hour base rate, but when you get into the 31 cents per kWh, then the installation of a smaller installation makes sense. Frank’s installation needs two inverters to pipe the peak production back into the grid. He told me that he overbuilt the installation. What you should do is start by looking at the inverters and depending on a price and kW rating of a single inverter, then put in only enough panels to feed that one inverter. Your electric bills would go down to maybe 40 or 50 bucks a month but you would not have to tie up so much money in the installation.

Now back to electrolysis as a solar power breakthrough. What the article shows is how desperate scientist and press agents are for any kind of attention they can get. I wrote the professor and tried to get clarification if he was really claiming a new electrolysis catalyst as a breakthrough. He never responded. I thought what the catalyst must be for is photosynthesis. This is called photodisassociation. That is where the sunlight breaks apart water into hydrogen and oxygen directly with sunlight, you don’t make electricity and then use electrolysis. As the Wikipedia entry on electrolysis points out, it is an inefficient process. It is an equilibrium reaction after all. When you have all those hydrogen and oxygen ions floating around in water they do love to just recombine and release heat. The Wikipedia article cites efficiencies from 50% to 80% and I can guarantee you the real efficiency of any practical large installation will be closer to the 50% range. Another thing worrying about the article is that in one breath they talk about how cheap the new catalyst is while later mention that they still need platinum for the other electrode. I am not trying to denigrate a cool scientific discovery, but tying it to solar power as a breakthrough is just intellectually dishonest.

Here is a paper from the pre-hype era of 2000 that points out the end-to end efficiency of solar-electrolysis is about 7.8%. Don’t get all excited about the 16% efficiency cited for gallium arsenide, a direct bandgap semiconductor that is far more photo-efficient. Those are the panels used in spacecraft and the reason is that they cost way too much for anything else. A few hundred watts will set you back $30,000. Here is another article from the era of hype about how nanotechnology will make electrolysis pay off. Notice what either the MIT article or this one demonstrates is the efficiency of the reaction, and I have to assume it is because catalysts and surface area will do nothing to increase the efficiency, other than perhaps making the electrodes smaller. Sure, it is great to have a low-cost renewable electrode on the hydrogen side of the reaction. Sure increasing surface area works great for capacitors and batteries. But please, lets look at system-level implications of this. Electrolysis sucks as a way to convert electricity to hydrogen, and hydrogen sucks as an alternative to liquid fuels since it is, ta da, a gas. So this whole magilla is about using a marginal power production method to feed an inefficient process to end up with a gas that, what, you can’t even run in lamps since it is explosive.

Here is an electrolysis article from the 1982 NY Times. It is a pre-hype article done by a paper with some integrity. Note how they say at the end that the process is too inefficient to be practical at the time. I hail the work of all the three science teams in the three articles I have cited. Their work is important, but I object to casting evolutionary improvements in general science as a major breakthrough, all in order to get funding. If you looking the MIT lab that make the “breakthrough” you will see that they were just funded with a big donation and it is doubtless they want to make the private donors feel like their money is making a difference. Funny thing is, that the catalyst discovery is significant, and all MIT has done is sullied the donation by casting this as some kind of solar power breakthrough.

When I say an article from 2000 is pre-hype I really mean it was in an alternative hype period. Back in 2000 the web was the thing. Remember that hype-fest? Billions of dollars tossed around and anyone that could put up an HTML page was given VC money. I had one VC tell me that it was a shame, he had several really great proposals for conventional software that he would like to fund, but if it did not tie into the internet or the web, he could not get them money. The same thing is going on right now with energy. If you have any hare-brained idea that remotely touches on energy you can get your VC funding. I say hooray. It is about time we hardware types got our windfall. It is estimated that he web-craze fiasco transferred 1 trillion dollars from the old-money finance types to a bunch of young software jockeys who now drive Ferraris and live in the hills. Yippee, I lets us hardware types try to get 2 trillion dollars. Here in Silicon Valley there is already a shortage of analog engineers and I hope it will soon spread to the whole country. Now is the time to jack up your salary and maybe even get into that energy startup. It will most likely crash like 90% of the web startups (remember koop.com?), but you will have some fun and have stories to tell your grandkids. And the best part is that our hardware hype-fest is just beginning. Expect another 5 years of glitz and glamour until reality hits.

So before you fall for all the hype, have a look at the Gartner Group’s chart of the hype cycle. My PR buddy tells me the guys at Gartner sit about in conference room roaring with laugher when they come up with these type of things, kind of like the Starbucks guys when they make up words like “Venti”. Still, you have to love terms like the “trough of disillusionment”. I am not trying to drag us all into that trough, just reminding you all that we are still climbing towards the “peak of inflated expectations”. Keep your head on and it won’t be so depressing when a lot of this alternative energy technology turns out to be hype. As the chart show, there will be some good to come out of all this and lets keep that in mind.


Related entries in: Analog | 


Reader Comments



at 8/14/2008 6:42:19 AM, Rich Marando said:
Your article overlooked a couple of important points: Companies like Nanosolar are now making low cost ($1/watt) printed solar panels. A fuel cell (either stationary or vehicular based) could be used to convert the hydrogen & oxygen back to electricity at night. With on site hydrogen & oxygen generation and storage, the distribution problem could be alleviated and fuel cell efficiency improved (compared to operation with plain air). Last but not least ... energy independence has a personal, societal and national security value that can''t be calculated in dollars and cents.

Best Regards, Rich



at 8/14/2008 10:52:26 AM, Greg T said:
You are right, of course, that healthy skepticism is an appropriate response to the MIT Technology Review article. Beyond that, I''m a bit confused by some of your comments. I believe that the scientist''s claim is that the described catalyst is a cheap and more efficient way to speed part of the reaction - the part dealing with the release of oxygen. Your comments about previous low efficiency rates of the described process using other catalysts seems off the mark, since low efficiency is precisely the problem that this catalyst is supposed to help address.





at 8/14/2008 12:21:12 PM, Meredith Poor said:
In the last couple of years Firefly Energy was supposed to have this fancy lead acid battery with huge energy density and far longer life (in terms of charge cycles) than existing lead-acid cells. I go back and revisit sites that showed up on my radar, and the site hasn't changed a bit, including a promise to roll out the battery in the "Summer of 2008". Is anyone home over there? Is this another hype round that is now history? Are they so busy making batteries that they can't update their site? I can name a few others (Konarka, Changing World Technologies, etc.). Anyone remember Cromenco and Vector Graphic? Or Interdata, or Scientific Data Systems? I can go back farther than that, if asked.



at 8/15/2008 10:01:51 AM, John Bailo said:
Scientific American and Science magazine reported the new process as 100% efficient.

The catalyst they use is a break through not only for efficiency, but because it is made of low cost, cheap and highly available materials.



at 8/16/2008 1:09:01 AM, Usbaldo Balderas said:
This might be old news, but Hamilton Sundstrand has already partnered with US Renewables Group to commercialize it's molten salt solar energy storing system. I'm a new employee there, is just recently there was an extensive article on one of the internal newspapers, and it claimed that the system has %98-%99 energy transfer efficiency. These are the types of efforts with real future that should be getting the spotlight in my opinion, as opposed to the usual 'MIT breaktrhoughs' like this that we are getting these days.





at 8/18/2008 1:41:33 PM, Teranko said:
This article is just the sort of disinformation the government relies on to inject enough confusion to make people think it doesn't work. Changing the world over from an oil based economy to a hydrogen based economy is daunting and must be done in a controlled manner so the real powers in place (oil company giants like Halliburton) that control the gov't can reap the economic benefits.



at 8/21/2008 3:57:08 PM, Robinson said:
As the comment above mentioned, this process is revolutionary because of its efficiency and the low cost of the materials needed. Coupled with other recent advancements in solar technology this is pretty revolutionary stuff. Think of a future without a power grid, self sustaining houses and neighborhoods, being able to fill your hydrogen fuel cell at home, etc... The possibilities are very exciting.



at 8/22/2008 12:59:37 PM, Paul Rako said:
Well, that people think society should pursue policies independent of what it costs shows that the green movement is a religious movement, not a scientific one. So if we bankrupt the whole world, and then starve all the poor with excessive food prices because of bio-fuel subsidies, that is OK because some upper middle class Americans need to feel morally superior to their peers? OK, first off, Scientific American in no way says that the process is 100% efficient. The efficiency number is completely absent from the press release, the Science abstract, everywhere. That is, you can bet, because it is not 100%. Wikipedia says "The number of electrons pushed through the water is twice the number of generated hydrogen molecules and four times the number of generated oxygen molecules." That is the therotical maximum. It simply cannot be 100% since when you have hydrogen ions and oxygen ions in water, there will be some recombination and hence, loss in efficiency. The most disturbing thing is positioning this as having something to do with solar energy. Solar does not need the help, peak loads in the US are great enough to absorb a whole bunch of solar. Trying to attach the completely impractical hydrogen economy onto solar is disingenuous at best. Filling your hydrogen fuel cell at home will make the American Trial Lawyers very happy but few other people. You have to compress the H2, what runs the pumps? That energy represents inefficiency. It is explosive-- what about your kid's safety, would you have a box of dynamite in the basement as well? This is being spun as revolutionary but it is claiming to enable solar power when it is not. It is cool having one electrolysis electrode be cheap, but read carefully and you will see the other one is still platinum. This is an evolutionary improvement in electrolysis chemistry, and that is wonderful. But it is wrong to attach this to photosynthesis, that does not require electricity to work, and solar power, that does not need hydrogen to store the energy when we have a perfectly good electrical grid that will suck up as much solar power as we could possibly make in the next 50 years. If you think CO2 is a sin and must be banished, you have to fall for the hydrogen economy as the only practical alternative. In fact hydrogen is a terrible fuel, even if this thing was 100% efficient. You can pine away for fuel cells but it seems to me that the cost of making proton exchange membranes will be very high for the foreseeable future and no, mass production will not magically lower the cost by a factor of 1000, which is what has to happen. Sure, maybe 50 years down the road fuel cells may be economically viable, but what nobody seems to get is that the difference between science and engineering is that engineering is concerned with economics whereas science just wants to get it to work once at any cost. It is very important we don't squander our money on pipe-dreams so we can use it to improve our lives on this planet. I agree we have to end subsidies to Halliburton and we also have to end them to Archer Daniels Midland, who makes a fortune off ethanol, a fuel that seems to have tripled corn costs the last few years. High-rise wind generators are economically feasible, solar panels will be in maybe 5 or 10 years. But to use costly solar power to bubble up hydrogen and then suffer all the problems with storage and transport, well, I don't think we will every have a hydrogen economy because H2 is just such a lousy way to store energy.



at 8/22/2008 2:40:01 PM, Max Miller said:
I noticed that you used "venti" as an example of a word made up by Starbucks. Actually venti is Italian for 20, which is the quantity (in fluid ounces) of coffe (or whatever you are drinking) in that size container.



at 8/26/2008 1:30:52 PM, Mike said:
Wow I just started subscribing to this publication and I am sorry to say that if this article/blog is indicative of the writing here, then please, cancel my subscription.
I was expecting something a bit more professional and cogent.



at 8/26/2008 1:59:01 PM, abc said:
Please proofread your articles. This is difficult to read with so many errors.



at 8/26/2008 2:09:33 PM, stiggle said:
MIT forgot to tell us that the Hydrogen generated is used for cold-fusion. This way they can get more out of it than the investors loose...



at 8/26/2008 2:15:10 PM, John said:
Mike... the observations made by Paul, are generally made to generate lively discussions.. And Paul loves to push people''s buttons .... BUT the real issues being brought up are generally valid... In this case, the point is not about science.... it is about wasting society''s resources in going forward... waste created by mis-information, hype and greed.



at 8/26/2008 5:19:35 PM, George said:
Here's a formula:
C55H72O5N4Mg commonly known as Chlorophyll, the stuff that makes photosynthesis work in plants and algae. Look up the structure on Wikipedia and you will see the Magnesium is surrounded by 4 Nitrogens. This spacial arrangement is what allows Chlorophyll to catalytically break down CO2 for the plant to digest it and use it for food production. A photon of light thus causes a breakdown that should not occur from an electrochemical energy point of view. This little miracle of nature is perhaps the type of catalytic arrangement that the MIT article is hinting about. If they have found a simple catalyst to cause Hydrogen and Oxygen to separate with less energy, then they may well be one to something.



at 8/27/2008 6:23:30 AM, Jeff said:
What about the water fuel cell from Stanley Meyer in Grove City, Ohio? Anybody checked this discovery out?



at 9/9/2008 4:50:36 PM, Ed said:
The Japanese produced a novel (and working) low-pressure hydrogen storage tank using organic-metallic ceramics years ago (mid-90's?) for use in fuel cell cars. The hydrogen is pumped into a porous ceramic matrix (aka "tank") and binds with the walls for storage. Hydrogen can then can be released at low rates for consumption, while preventing fast rate release which could lead to explosions. This type of storage does not require hydrogen pumps, and is completely safe from mechanical impacts (e.g. even car crashes...), so the earlier statement of "having a box of dynamite in the basement" would not apply.

Recently, Caltech and the University of Maryland have been studying a new compound which should provide even better hydrogen storage density:
Search on "ceramic hydrogen storage" in Google.



at 7/27/2009 7:29:50 PM, Anon said:
This comment is a bit late...

I hope you were joking about the water fuel cell...

Because if you weren't I am sorry but you are mentally fricken retarded.

If the fuel cell were to work it breaks the first and second laws of thermodynamics.



at 8/1/2009 11:12:08 PM, beninjoseph said:
if you made atleast some power you could decrease global warming..... and save the future of our children

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