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Monday, July 28, 2008

Lead-free soldering more reliable after all?

Jul 28 2008 5:15PM | Permalink | Email this | Comments (13) |
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Thought I would touch on the subject of lead-free soldering again as you, our Critical Links readers, always provide me with an interesting response. Whether we like it or not, and even allowing for the unsatisfactory way that it arrived and the lack of life-cycle assessment before lead was banned from solder, it seems that lead-free soldering is here to stay.

A few days ago, a UK customer wrote to me detailing their lead-free experience.

“A couple of years or so before the deadline for going lead free, we began experimenting with the use of lead-free solder.  At that time, the biggest problem going entirely lead free was the lack of information available. So one had to assume that lead-free resistors and capacitors were not available.

The initial finding was that lead-free soldering (all hand soldering in our case) was more costly. For example, $50 for the lead-free equivalent of a $30 reel of 60/40, and $10 for lead-free plumbing solder. Soldered copper pipe joints are easier and better with lead-free.

Electrical soldering took longer than with 60/40, and it helped to use extra flux. Soldering anything larger than 0.5-mm2 cables was almost impossible, and lead-free solder would not flow around to the blind side as did 60/40.

The Mec-Seal coating on PCBs is excellent, and makes soldering easy. But it is easier to get dry joints which look OK than it was with 60/40 because the component lead is not adequately wetted.  When soldered, the mechanical strength of the joint seems better with lead-free solder, suggesting better reliability.

When unsoldering items, this is much harder than it was with 60/40 because of the much longer time needed to get heat to flow from the soldering iron bit into the harder solder. A drop of 60/40 helps a lot here, bridging between two convex surfaces.  Even then, working lead-free is a much slower process.

While lead-free works well on a new circuit board, I have concluded that there is a case for tin-lead solder for any situation where you have to solder something in a hurry, especially when jointing cables.”

So, what do you think, does lead-free suggest better reliability?

Are you becoming more comfortable with the process and what challenges have you faced?

As always, I would be delighted to hear from you. Post your comments below.

About the author
As director of legislation and environmental affairs, Gary Nevison is Newark's and Farnell's spokesperson and customer interface on legislation that affects the electronics industry, such as the ROHS (all variations around the world, including China ROHS), REACH, EuP, and WEEE directives. For more on Gary, click here.


Reader Comments


at 7/30/2008 2:36:01 PM, Richard said:
You have to be kidding... the industry has already identified the relative reliability of Pb-free joints... whether the joint is better than the SnPb or worse depends on the strain rate being applied to the joints. Everything about lead-free is costing the consumers and it will never show up as a benefit to mankind. Companies around the globe have invested millions of dollars to comply with political idiots in the EU.

at 7/30/2008 3:35:21 PM, bwl said:
This sounds like a pretty narrow definition of reliability for a particular application. I for one am still confused as to what the real failure rate is due to tin whisker related problems on typical consumer high density packaging. Are any manufacturers actually analyzing failures and publishing results that stand up to scrutiny? Seems like cell phones, due to their high volumes, small size, and rough environment would be ideal to answer this question. So far all I find are old "prediction" articles and nothing with good factual data.

at 7/30/2008 4:17:23 PM, desert rat said:
I have microscopic pics here that would send you running into a house afire before you would trust Pb-free junk. Plating in thru-holes breaking loose under <200 thermal cycles, complete rows of balls cracking and breaking-loose on BGAs, all creating opens in the signal path (some of these showed-up under shock and vibe testing too). Pb-free may be OK for Chinese-made junk consumer products that fail in 3 months, but not in electronics that are used in critical systems. Anyone who uses Pb-free solders has a faith-based engineering degree...

at 7/30/2008 4:17:50 PM, Stiggle said:
Brittle joints, poor wetting, higher heat and longer solder times compared to lead based solder means less reliability. Higher heat and longer times at higher heat can’t be as good for the semiconductors either! This is why the military has programs to convert lead-free components and use lead based solder in mission critical and military applications. What more can be said?

at 7/30/2008 5:44:20 PM, John said:
I concur with most of the comments... ROHS - the paving on the road to hell (good intentions).... Shear strength is likely to be better on a well formed ROHS solder joint, but that is not a valid indicator of joint quality. Many more valid indicators show the old tin/lead solder is much more reliable (compliance, no tin whiskers, reduced variations in joints strength,etc....) Then there is the lack of research on the total impact on the environment before putting the damn law into effect. Indications of the facts at present- zero gain or possible negative impact on earth. and there isn't anything I can do about it....

at 7/31/2008 1:36:48 AM, VCR85 said:
What more can one say, the earlier comments cover it all. The wholme RoHS deal isan exercise in political correctness in the EU which will cost us all dear. I recently had to do some work on a Chinese product which was actually well-designed with good quality materials and components but had real reliability problems due to use of lead-free solder.

at 7/31/2008 10:11:25 AM, AV said:
And one more: all this Lead-Free campaign in electronic products looks even more ridiculous when you consider tons and tons of lead in running around automobile lead-acid batteries.

at 7/31/2008 11:13:25 AM, Darren Holdstock, UK said:
There's nothing in the OP quoted letter that suggests better reliability with RoHS solder - a vague feel for increased mechanical strength is, well, a vague feel, not sound science. I note with dismay that Farnell are completely discontinuing all incandescent light bulbs (thanks for that, now our machine shops are made more dangerous by strobing fluorescents making rotating objects appear stationary or slow-moving), and I can guess that maybe it's the same twisted logic that connects increased RoHS solder reliability with one vague letter that really doesn't suggest anything of the sort. Farnell used to be a great company to deal with, but they've dropped the ball on so many levels in the past year or so, and such tenuous fluffery as the OP is just another fine example.

at 8/5/2008 11:57:51 AM, W Clark said:
The author is obviously not a industry expert in this field. The letter is written as if the major impact of lead free is hand soldering. No mention of the defects we encounter every day. I have read his other articles, this one is over the top. Newark it's time to fire Gary Nevison and find a person with some experience in the industry.

at 8/6/2008 3:56:32 PM, Joe Money said:
To the 2 comments above: You are the ball droppers and clearly ar not experts on Rohs. Stop complaining about light bulbs and manage your businesses.

at 8/12/2008 8:17:55 AM, Darren Holdstock, UK said:
I know who you are, Joe Money - you''re Farnell''s mum. My business is EMC testing - while you''re busy with the spit and handkerchief, could you ask your lad how we can illuminate our EMC chambers? All that expensive mumetal and ferrite does no good if there''s a massive source of interference dangling from the ceiling. And it''s a serious point about the rotating machinery - the only real non-incandescent option is running 3 sets of fluorescents off 3 different mains phases and relying on the overlapping of the short afterglow. It''s not all bad, as Farnell have been pretty good on RoHS changeover management, which must have been a massive task that would stretch any supplier.

at 8/12/2008 11:45:23 AM, FormerKidWhoSleptInLeadPaintedCrib said:
Great! Now that Lead Free is reliable, let's start using them for military planes, missiles, and military electronics, jumbo jets, and pacemakers and life support systems in hospitals.

at 8/13/2008 2:59:50 AM, Gary Nevison said:
Clearly I am not on W Clark's Christmas card list! All this article did was share a letter with you that I received from a customer in the UK.I pass no personal comment on lead free solder other than to say manufacturers are unlikely to turn back now. Also, had adequate research taken place back in 2003 I doubt lead in solder would be banned today. Likewise there is little point in writing a blog around soft subjects. I aim to put across an objective view on some of the more controversial issues.I do hope that you take the time to read future blogs and I look forward to hearing from you again.

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